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Since 1904
trade, storage and analysis of chemical and petrochemical products
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What is a "coastal terminal"?
Why is the coastal terminal of Attilio Carmagnani "AC" S.p.A. particularly strategic?
Isn't it dangerous?
What type of checks and inspections are carried out?
Who carries out these checks and inspections?
As a citizen, what guarantees do I have regarding emissions into the air and atmosphere?
Are there other similar activities in the same area?
How many people are involved in these activities?
What solutions have been adopted in other European cities for the location of coastal terminals?
Are Carmagnani and Superba the same company?
What does "petrochemical" means?
What type of products are stocked by Carmagnani? What are they used for?
What is "flash point"?
How much of the petroleum products of the port handled by Carmagnani?
What does Attilio Carmagnani make?
We live near the railway tracks and since the Viareggio disaster rail tankers concern us. Could something like that happen here?
Could an accident like the one that happened in 1987 occur at Attilio Carmagnani "AC" S.p.A.?
What would the consequences of a major accident at the terminal be?
Is there an External Emergency Plan of the area in case of accident? Is the general population informed?

What is a "coastal terminal"?
A coastal terminal is a facility consisting of equipment and systems (mainly tanks, piping and pumps) for receiving, stocking and delivering products. No production activities are carried out in coastal terminals. Products are simply stored there in tanks. The features of these terminals is that they are located near the sea, close to ports to which they are connected by means of pipes for transporting products by ship. For this reason, coastal terminals are strategically important for the national economy.

Why is the coastal terminal of Attilio Carmagnani "AC" S.p.A. particularly strategic?
Most of the goods supplying the entire North West of Italy pass through the Port of Genoa. This port is the most suitable in Italy because it is closer to destination industries, not prone to fog like the ports of the Adriatic Sea and because of the deeper sea can be used by larger ships. Furthermore, the coastal terminal of Attilio Carmagnani "AC" S.p.A. is the only one in the province of Genoa to be authorised for haulage of chemical products on railways.

Isn't it dangerous?
The dangerousness of coastal terminals is classified by law according to the type and amount of stocked products. More specifically, the terminal of Attilio Carmagnani "AC" S.p.A. is classified as "hazardous" in accordance with Italian Law 334/99 because flammable products and products harmful for sea life are stocked there. As confirmed, among others by the Genoa City Authorities, "a high risk plant is not necessarily a danger for the population if adequate safety measures are adopted in system design, construction, management and maintenance". The law requires the company to adopt strict procedures for compliance and inspections by the Fire Brigade Regional Technical Committee (CTR, formed by the experts from the Fire Brigade, ARPAL, the Region, the Province and the City). After having examined the Safety Report written by Attilio Carmagnani "AC" S.p.A., the CTR concluded that the terminal is compatible with its location.
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What type of checks and inspections are carried out?
Checks and inspections of various type are carried out continuously at the terminal of Attilio Carmagnani "AC" S.p.A.: internal, by third parties, on systems and on operator behaviour. In other words, checks and inspections are run on water drains, emissions into the atmosphere, noise, waste, soil, systems, devices and equipment. The Safety Management, Environment and Quality systems are also constantly monitored.

Who carries out these checks and inspections?
Checks and inspections are continuous and carried out by several different organisations. In particular:
  • continuous internal checks and inspections by specialised engineers;
  • checks and inspections by Control Organisations, including the Fire Brigade, ARPAL (Regional Agency for Protection of the Environment), the Province, the City, the Health Board, the Region, the Labour Inspectorate, NOE, the Environmental Police, the Port Authorities, the Customs Authorities, the Metric Office and the Finance Police
  • checks and inspections by suppliers, including Railways and Certification Institutes
  • checks and inspections by customers, including Polimeri Europa (ENI Group)

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As a citizen, what guarantees do I have regarding emissions into the air and atmosphere?
Attilio Carmagnani "AC" S.p.A. monitors emissions into the environment in accordance with a specific authorisation issued by the Province of Genoa. This authorisation requires emissions to be conveyed into an ultramodern abetment system. The efficiency of this system must be monitored, as must the quality of the environment air in the area surrounding the terminal. The results of the various checks and inspections are submitted to the respectively competent authorities for independent verification.
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Are there other similar activities in the same area?
Other activities are present in the area surrounding the coastal terminal. These include the chemical-goods analysis laboratory of Analisi & Controlli S.p.A., the offices of forwarding agents G. M. Puppo S.r.l. and other companies operating in the field of chemical product sales and logistics, such as Metachem, Laboratorio Cosulich, Watson Gray, Adam Shipping and Saybolt. The presence of other complementary companies makes this an industrial district of key importance.
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How many people are involved in these activities?
Attilio Carmagnani "AC" S.p.A. alone has a staff of approximately 30, while other 18 people are employed at the chemical laboratory of Analisi & Controlli S.p.A. Other professionals work for Attilio Carmagnani "AC" S.p.A. in addition to employed personnel totally a staff of more than 60 people.
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What solutions have been adopted in other European cities for the location of coastal terminals?
Coastal terminals are located in or nearby the areas of major ports across Europe, just like the terminal of Attilio Carmagnani "AC" S.p.A.
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Are Carmagnani and Superba the same company?
No: Attilio Carmagnani "AC" S.p.A. is a family-run company owned by the Carmagnani, Bonetti and Rossi families, while Superba S.r.l. belongs to the PIR Group (Petrolifera Italo Rumena).
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What does "petrochemical" means?
The word "petrochemical" refers to operations related to refining of petroleum and derived products. Attilio Carmagnani "AC" S.p.A. does not process the stocked products in any manner and all activities are classified as logistic.
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What type of products are stocked by Carmagnani? What are they used for?
Attilio Carmagnani "AC" S.p.A. today mainly stocks liquid solvents used by the companies who own the material, particularly for the production of plastic and paint thinners. Since the end of 2010, Attilio Carmagnani "AC" S.p.A. has been authorised to stock mineral oil, including biodiesel of vegetable origin and lubricant oil.

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What is "flash point"?
The flash point of a combustible is the minimum temperature (at the pressure of 1 atm) at which the substance produces sufficient vapours to form a flammable mixture with oxygen. Flammable liquids are classified for the purposes of safety according to Italian Law 31/07/1934 specifically according to their flammability as follows:
  • Category A (Ti < 21 °C): petrol, alcohol; these products are the most dangerous because they are easily flammable also at ambient temperature and must be kept away from sparks.
    No Category A products are stocked at the terminal of Attilio Carmagnani "AC" S.p.A.
  • Category B (21 °C ≤ Ti ≤ 65 °C): e.g. xylene, cyclohexanone
  • Category C (Ti > 65 °C): e.g. biodiesel, lubricant oils, alkylated products, white spirit

For example, the flash point of petrol is -40°C. The flash point of o-Xylene is +32°C.

Links to the main product stocked and handled at the terminal:
o-Xylene
Cyclohexanone
Xylene
Isobutanol
Butanol
Pseudocumene
White spirit
Lubricant oil
Biodiesel

o-Xylene
Intermediate liquid for the production of phthalic anhydride, which is turn is used as intermediate product in the synthesis of other chemical products (colourings, insecticides, plasticisers, resins, pharmaceuticals). Other uses of o-xylene are in the field of bactericides, herbicides and lubricants.
Flash point: 32°C
% on total products handled (t/year): 50%.
Approximately 60% of all o-xylene is delivered by means of rail tankers.

Cyclohexanone
Intermediate key liquid for the production of caprolactam, adipic acid, nylon 6 and nylon 6-6. The latter are the two nylon polymers most used for the production of fibres for textile applications and industrial applications such as, in particular, plastic and rubber. Cyclohexanone is further used as solvent for gluing and assembly of plastic parts for medical and surgical devices and as additive in inks.
Flash point: 46°C
% on total products handled (t/year): 25%

Xylene
Liquid mainly used as paint component and thinner. It is also used as solvent for printing, for processing rubber and leather, as cleaning agent for steel and as pesticide. Small amounts may be found in jet fuel and diesel. Another frequent use is in test laboratories for processing histological samples.
Flash point: 25°C
% on total products handled (t/year): 2%

Isobutanol
This liquid is mainly used as solvent and as intermediate compound in the synthesis of other substances. It is used in the field of insecticides.
Flash point: 28°C
% on total products handled (t/year): 0.2%

Butanol
This liquid is mainly used as solvent in the production of paint. It prevents clear varnish from clouding when dried in damp environment. It is also used as intermediate product in the synthesis of ethers and esters, in the synthesis reactions of which it doubles as solvent.
Flash point: 28°C
% on total products handled (t/year): 0.2%

Pseudocumene
This liquid is fundamentally used for the production of carboxyphthalic anhydride, which is used above all in the field of resins (for the production of insulating varnish for electric cables and paint powders and, in part, for the production of special plasticisers, such as electric cable sheaths, roofing panels, imitation leather, dashboard and automotive interiors). Other minor uses are in the field of pharmaceuticals, colourings, and plasticisers.
Flash point: 44°C
% on total products handled (t/year): 5%

White spirit
This liquid is used as thinner in paint production.
Flash point: 64°C
% on total products handled (t/year): 2%

Lubricant oil
Lubricant oil storage started in 2011 after having obtained authorisation by the Province of Genoa. The oils currently stored and handled are used as lubricants for mechanical parts. In the future, we plant to store technical and pharmaceutical white oil used for making pesticides, in the cosmetic, winemaking and food-processing industry and for making plastic and rubber intended to come into contact with cosmetics, food and beverages. By way of example, many cosmetics for infants (body oil, nappy creams) contain this product as main ingredient.
Flash point: approximately 200°C

Biodiesel
Non-hazardous liquid of vegetable origin used mainly as automotive fuel.
Flash point: > 101°C

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How much of the petroleum products of the port handled by Carmagnani?
As indicated on the website of Porto Petroli di Genova S.p.A. the chemical products handled by Carmagnani and Superba jointly total only 2%.

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What does Attilio Carmagnani make?
Nothing at all! Attilio Carmagnani "AC" S.p.A. only stocks finished products and markets chemical and petrochemical products.
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We live near the railway tracks and since the Viareggio disaster rail tankers concern us. Could something like that happen here?
The possibility of an accident like the one which occurred in Viareggio could be related to the transit of rail tankers carrying LPG on the Genoa-Ventimiglia railway line. This has nothing to do with Attilio Carmagnani "AC" S.p.A. Attilio Carmagnani "AC" S.p.A. neither handles nor stores gas. Attilio Carmagnani "AC" S.p.A. only handles category B and C liquids in tankers.
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Could an accident like the one that happened in 1987 occur at Attilio Carmagnani "AC" S.p.A.?
An accident like the one which occurred in 1987 is today considered unlikely due to the lack of category A products and because of the technological progress of the past 20 years. The main measures adopted by Attilio Carmagnani "AC" S.p.A. for preventing accidents are:

PRECAUTIONS ON SYSTEM LEVEL
The main precautions adopted on system level are:
  • Only products with flash point higher than 21°C (Category B and C) are stored.
  • Tanks containing substances with lower flash point are provided with a plenum containing nitrogen and an alarm is set off if a percentage of oxygen higher than 4% is detected in the tanks.
  • Tanks are underground (or comparable to being underground in terms of thermal exchange with the environment) allowing to keep stocked products cooler than ambient temperature during the summer.
  • Larger tanks are made of reinforced concrete with internal carbon steel lining.
  • Tanker loading arms provided with two safety mechanisms (high and extra high) for stopping filling operations.
  • Automatic litre counter for loading rail tankers.
  • Tamperproof valves on rail tanker arm terminal segments.
  • Device for stopping the pumps if liquid is detected in rail tank vapour recovery pipes.
  • High and very high alarm system to prevent overfilling storage tanks.
  • Vapour abetment system from tank breathers and vehicle loading points.
  • System for detecting the presence of flammable vapours in high confinement degree locations. These detection systems automatically turn on extraction fans of suitable capacity and alarms in manned zones.
  • Electrical systems made to prevent sparks.
  • Adequate earthing and lightening protection system.
  • Test plans and periodical replacement of all components particularly subject to wear (e.g. tanker and rail tanker loading arms and flexible tubes in pump rooms).
Measures for preventing pollution in case of accidental product spillage:
  • Tank pools have adequate capacity and bottoms made of waterproof material.
  • Pump rooms have waterproof floor and walls.
  • Tanker transfer points are slanted to convey any spillage towards collection grids by means of tube systems and take the substances towards waterproofed tanks of adequate capacity.
A well point system monitors presence of pollutants in the soil and, if required, collects them.

PRECAUTIONS ON OPERATIVE LEVEL
Precautions on operative level essentially avoid release, fire and explosions and mainly consists of:
  • Periodical checks and inspections on the state of preservation of all devices containing products.
  • Periodical safety system operation checks (tank breather valves, cut-off systems, vehicle filling stop system, plenum system, abatement systems, high level tank alarms, vapour abatement systems).
  • Adoption of procedures aimed at minimising operative errors from causing product spillage during loading/unloading operations from vehicles. Particular attention is devoted to preventing tanker movement before the entire transfer operation is complete.
  • Adoption of procedures aimed at preventing overfilling of tanks by periodically checking operation of instruments and alarms used to carefully measure levels during transfer operations. Reliable, expert personnel is employed to ensure that checks are thorough.
  • Adequate incoming product batch programming according to residual tank capacity.
  • Adoption of careful reclaiming procedures of devices aimed at avoiding the formation of flammable atmosphere inside tanks and pipes when they are decommissioned for maintenance and inspections.

MEASURES ADOPTED FOR PREVENTING RISKS DUE TO HUMAN ERROR
Measures are adopted on organisational and procedural level to reduce the possibility of accidents caused by system operating errors. This is possible by adopting periodical training and information schemes described in the safety management system manual. These plans comply with the requirements set forth in standards and regulations. Other standards and operative instructions are provided. The utmost importance is devoted to personnel training.

PRECAUTIONS IN CASE OF NATURAL DISASTERS, EXPLOSIONS AND FIRE
The system was designed in accordance with the standards in force when it was built (see Italian Law 31/07/1934), including precautions concerned stress of natural and accidental origin.
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What would the consequences of a major accident at the terminal be?
Calculations conduced in the Safety Report, analysed and approved by the Fire Brigade Regional Technical Committee indicate that the credible effects of an unlikely major accident would remain within the confines of the plant.
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Is there an External Emergency Plan of the area in case of accident? Is the general population informed?
Yes, an External Emergency Plan was written by the Genoa Prefecture. In accordance with Law 334 of 17/8/1999, the Mayor is responsible for informing the population on the risks related to certain hazardous substances present in plants located within the town boundaries. The population is informed by distributing leaflets compiled by the owners of the hazardous industrial activities complete with indications, contained in the external emergency plan written by the Prefecture, of the safety measures and behaviours to be followed in case of major accident.
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ATTILIO CARMAGNANI "AC" S.p.A VIA DEI REGGIO, 2 - 16155 GENOVA  Tel.+39.010.6006.1 - Fax.:+39.010.6006.230 management@carmagnani.com
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